Photophysics beamline

Beamline overview

The beamline is being used extensively for UV-VUV spectroscopy of molecules of current interest in Atmospheric sciences, Astro-physics, Astro-chemistry, Combustion, Plasmas, Semi-conductor etching, medical applications etc. The scopes of experiments which can be carried out using this beamline include:

  1. Photoabsorption studies of atoms, molecules and radicals in gas phase, condensed phase
  2. Photochemistry of molecules in excited states consequent of VUV photon absorption
  3. Optical properties of materials and testing of photon detectors
The Beamline
Gas  Cell
The Beamline
Gas Cell

Beamline parameters & Optical layout

  1. Beamline uses a constant deviation angle Seya-Namioka monochromator with 1200/2400 G/mm gold coated spherical gratings
  2. The first optical element of the beamline is a vertically deflecting and horizontally mounted toroidal mirror, TM1, which accepts 5.6 mrad (H) and 41 mrad (V) of the emitted bending magnet radiation
  3. TM1 focuses the light vertically on to the entrance slit S1
  4. The second mirror i.e called as post focusing optics is a vertically deflecting and horizontally mounted toroidal mirror, TM2
  5. Image spot size is 1mm × 1mm
  6. Flux 108photons/sec at the sample position
Optical layout

Research Activity

Research Activity

Research Highlights

  1. Spectroscopy studies on molecules carried out are part of contributions towards international spectroscopy data bases Science-softCon UV/Vis+ Spectra (http://www.uv-spectra.de) and MPI-Mainz UV/VIS Spectral Atlas of Gaseous Molecules of Atmospheric Interest’ www.uv-vis- spectral-atlas-mainz.org
  2. Measurement of photoabsorption cross-sections for molecules of interest in Astro-chemistry, Plasma Physics and Green solvents


1. "Exploration of Gamma irradiations effects on the Structural, Spectral Characteristics, Thermomechanical behaviour and Optical constants in <011> Oriented Glycine-DiGlycinium Sulphate Single Crystals " ,
V.C. Bharath Sabarish, A. Durairajan, M.P. Graca, M.A. Valente, J. Gajendiran, B.N. Rajasekhar, Rajeev Bhatt, Indranil Bhaumik, A.K. Karnal, A.K. Sinha, M.N. Singh, S. Gokulraj, G. Ramesh Kumar,
1248, 131450, 2021, Journal of Molecular Structure
2. “Electronic states of nitromethane: experimental and theoretical studies “,
Aparna Shastri, Asim Kumar Das, Sunanda K., B.N. Rajasekhar,
276, 107933, 2021, Journal of Quantitative Spectroscopy and Radiative Transfer
3. “Preparation of Low Cost NaCl Single Crystal for IR Optical Window Applications",
V.C. Bharath Sabarish, A. Durairajan, J. Gajendiran, B.N. Rajasekhar, Asim kumar Das, S. Gokul Raj, G. Ramesh Kumar,
J32, 24971–24979, 2021, Journal of Materials Science: Materials in Electronics
4. “Spectroscopy of structural isomers of pentanes: An experimental and theoretical study”,
Asim Kumar Das, Sunanda K. and B.N. Rajasekhar,
1245, 131126, 2021, Journal of Molecular Structure
5. Electronic and Vibrational Spectroscopy of Ethyl Methyl Carbonate: A comparative experimental and theoretical study,
Asim Kumar Das, Sunanda K., and B.N. Rajasekhar,
272, 107789, 2021, Journal of Quantitative Spectroscopy and Radiative Transfer
6. “Influence of Nickel (Ni7+) Swift Heavy Ion (SHI) Irradiation on the Optical, Topological, Dielectric, Piezoelectric and Ferroelectric Properties of Oriented Ferroelectric Triglycine Sulphate Single Crystals, “,
Bharath Sabarish V.C, Durairajan A. Graca M.P. Valente M.A. Gajendiran J. Rajasekhar B.N. Asim kumar Das; Bhatt Rajeev, Bhaumik Indranil, Karnal A.K. and Gokul Raj S.,
138389, 769, 2021, Chemical Physics Letters




1. “Surface and bulk modifications in gamma Irradiated <011> oriented ferroelectric Triglycine Sulphate (TGS) single crystals”,
V.C. Bharath Sabarish, G. Ramesh Kumar, S. Gokulraj, A. Durai Rajan, E. Venkata Ramana, Igor Bdikin, B.M.S. Teixeira, Nikolai Sobolev, M. P. F. Gra_ca, M.A.Valente, B.N. Rajasekhar
– 222, 165326, 2020 Optik .
2. “The electronic absorption spectrum of Anisole studied by photoabsorption spectroscopy and quantum chemical calculations”,
Aparna Shastri, Asim Kumar Das, B.N. Rajasekhar,
Journal of Quantitative Spectroscopy & Radiative Transfer 242,106782, 2020
3. “6-Hydroxycoumarin using experimental and theoretical methods”,
D. Vijay, Y. Sushma Priya, M. Satyavani, Asim Kumar Das, B.N. Rajasekhar and A. Veeraiah,
Spectro Chimica Acta Part A: Molecular and Bio-molecular Spectroscopy, 229, 117930, 2020
4. “Infrared attenuation due to phase change from amorphous to crystalline observed in astrochemical propargyl ether ices”,
K.K. Rahul, J.K. Meka, S. Pavithraa, P. Gorai, A. Das, J.-I. Lo, B.N. Rajasekhar, B.-M. Cheng, P. Janardhan, A. Bhardwaj, N.J. Mason, B. Sivaraman,
Spectro chimica Acta Part A: Molec. and Biomolec. Spectrosc., 231, 117797, 2020




1. “Electronic spectroscopy of ethanol: An experimental and theoretical study”,
Sunanda K, Asim Kumar Das and B.N. Rajasekhar,
Journal of Quantitative Spectroscopy & Radiative Transfer, 237, 106609, 2019
2. “Quantum chemical calculations and FTIR, UV light interactions on benzofuran-2- carbonyl chloride”,
D. Vijay, Asim Kumar Das, B N Rajasekhar and A.Veeraiah,
Journal of Emerging Technologies and Innovative Research 6, 169-179, 2019.
3. “Experimental and theoretical studies on the absorption spectra of n-dodecane in the IR and VUV regions”,
Kiran Kumar Gorai, Aparna Shastri, Param Jeet Singh and S. N Jha,
Journal of Quantitative Spectroscopy and Radiative Transfer 236, 106582 2019




1. “Spectroscopy of diethyl carbonate, a green solvent: An experimental and theoretical study”,
Asim Kumar Das, B. N. Rajasekhar and Sunanda Krishnakumar,
Journal of Quantitative Spectroscopy & Radiative Transfer 21, 53 - 62, 2018
2. “Experimental and computational VUV photoabsorption study of Dimethyl Carbonate: A Green Solvent”,
Asim Kumar Das, Sunanda Krishnakumar and B. N. Rajasekhar,
Journal of Quantitative Spectroscopy & Radiative Transfer 217,116 - 125, 2018.
3. “Development of an experimental set-up for low temperature spectroscopic studies of matrix isolated molecules and molecular ices using synchrotron radiation”,
Param Jeet Singh, K. Sundararajan, Aparna Shastri, Vijay Kumar, Asim Kumar Das, P.K. Kush and B.N. Rajasekhar,
Journal of Synchrotron Radiation 25, 1425 - 1432, 2018





1. “Spectroscopy of N,N-dimethylformamide in the VUV and IR regions: Experimental and computational studies”,
Aparna Shastri, Asim Kumar Das, Sunanda Krishnakumar, Param Jeet Singh, and B. N. Raja Sekhar, Journal of Chemical Physics 147, 224305, 2017
2. “Electronic spectroscopy of ethyl bromide probed by VUV photoabsorption and quantum chemical calculations
A. Shastri, P. J. Singh, S. Krishnakumar, A. K. Das and B.N. Rajasekhar,
Phys. Chem. Chem. Phys., 19, 6454 - 6469, 2017





1. “Experimental and computational studies on the electronic excited states of nitrobenzene”,
Sunanda K, Asim Kumar Das, Param Jeet Singh, Aparna Shastri and B.N. Rajasekhar,
Journal of Quantitative Spectroscopy & Radiative Transfer 184, 89 - 99, 2016
2. ”Photoabsorption spectra of tetramethylsilane in the energy region 6 - 11.5 eV”,
Asim Kumar Das, B.N. Raja Sekhar Sunanda Krishnakumar,
Indian Journal of Physics (India) 90, 1 - 8, 2016
3. ”Vibrational modes in excited Rydberg states of acetone: A computational study”,
Aparna Shastri and Param Jeet Singh,
Journal of Quantitative Spectroscopy and Radiative Transfer 173, 92-105 (2016)



Science Highlights

Science Highlights

Science Highlights

Science Highlights

Team members

  1. Shri Asim Kumar Das
  2. Dr. Aparna Shastri
  3. Dr. K. Sunanda
  4. Dr. B.N. Rajasekhar
  5. Dr. Dinesh Udupa
ATOMIC AND MOLECULAR PHYSICS DIVISION, BARC

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